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CasNo: 551-68-8
MF: C6H12O6
Appearance: Sweet syrupy liquid
Enzyme inhibitor |
This ketohexose (FW = 180.16 g/mol), also known as D-ribo-2-hexulose and reportedly fpound in cane molasses, has epimers of D-psicose are Dfructose, D-sorbose, and L-tagatose. D-Psicose is an alternative substrate for fructokinase. The structural composition of D-psicose at 27°C in D2O is 22% a-pyranose, 24% b-pyranose, 39% a-furanose, and 15% bfuranose. Target(s): ketohexokinase, or hepatic fructokinase; also alternative substrate. |
Definition |
ChEBI: The D-enantiomer of psicose. |
InChI:InChI=1/C6H12O6/c7-1-3(9)5(11)6(12)4(10)2-8/h3,5-9,11-12H,1-2H2/t3-,5-,6+/m1/s1
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dihydroxyacetone
Glyceraldehyde
DL-dendroketose
fructose
sorbose
lyxo-2-hexulose
ribo-2-hexulose
Conditions | Yield |
---|---|
sodium hydroxide;
In
water;
at 25 ℃;
for 1h;
Product distribution;
further catalysts;
|
8 % Chromat. 2 % Chromat. 40 % Chromat. 32 % Chromat. 18 % Chromat. |
dihydroxyacetone
Glyceraldehyde
DL-dendroketose
fructose
sorbose
lyxo-2-hexulose
ribo-2-hexulose
Conditions | Yield |
---|---|
sodium hydroxide;
In
water;
at 25 ℃;
for 1h;
Product distribution;
further catalysts;
|
8 % Chromat. 2 % Chromat. 40 % Chromat. 32 % Chromat. 18 % Chromat. |
D-glucose
D-Allose
Penta-O-acetyl-keto-D-psicose
D-Fructose
D-allose osazone
methyl-[tetra-O-methyl-psicofuranoside
D-altrose
D-Allose